In short, anion batteries are a class of batteries that have great development prospects in addition to cation batteries. The research of anion storage is not only applied to the development of various anion batteries, but also can be extended to DIBs based on various anions and cations.
Conclusion and outlook Anion batteries are one of the most promising and alternative storage technologies. Compared with LIBs , anion batteries exhibit higher theoretical capacity and energy density, as shown in Fig. 12 a. However, practical capacity and energy density of anion batteries display obvious difference.
However, the effect of the anion on the properties of batteries is still unclear. Herein, lithium bis (trifluoromethylsulfonyl)imide (LiTFSI) and lithium difluoro (oxalato)borate (LiDFOB) are selected to investigate the working mechanism of anions in solid and liquid systems.
As promising alternatives to lithium-ion batteries, rechargeable anion-shuttle batteries (ASBs) with anions as charge carriers stand out because of their low cost, long cyclic lifetime, and/or high energy density.
According to the previous literatures, we know that researchers have summarized the progress and challenges of certain anion storage, such as fluoride-ion batteries (FIB) , chloride ion battery (CIB) , and DIBs . However, an overall review of various anion storage batteries has not been reported.
Lithium salts exert a great influence on the electrochemical performance of lithium metal batteries. Dissociated Li-ions present rapid transfer dynamics through solvation with a solvent in liquid batteries or complexation–decomplexation with a polymer in solid batteries.
Design of sulfonimide anions for rechargeable lithium batteries
Design of sulfonimide anions for rechargeable lithium batteries Xingxing Wang, Wenfang Feng, Zhibin Zhou, and Heng Zhang* Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology 1037 Luoyu Road, Wuhan 430074, China
Unlocking the Use of LiCl as an Inexpensive …
Lithium chloride (LiCl) is an inexpensive and environmentally friendly salt abundant in the ocean. However, the insolubility of LiCl in conventional electrolyte solvents prevents …
Breaking the molecular symmetricity of sulfonimide anions for
Lithium metal batteries operating under extreme conditions are limited by the sluggish desolvation process and poor stability of the electrode–electrolyte interphase.
Breaking the molecular symmetricity of sulfonimide anions for …
Wu, F. et al. Dual-anion ionic liquid electrolyte enables stable Ni-rich cathodes in lithium metal batteries. Joule 5, 2177–2194 (2021). Article Google Scholar
Electrolyte solvents for high voltage lithium ion batteries: ion ...
All findings highlight the crucial importance of specific anion effects in combination with molecular details of solvation, and advocate the use of adiponitrile as a beneficial solvent in modern lithium ion battery technology with high voltage electrodes.
Borates vs. aluminates: comparing the anion for lithium-ion batteries …
Lithium borate and aluminate salts bearing a hexafluoroisopropoxy ligand have been prepared and investigated for use in lithium-ion batteries and Cu‖Li cells. Lithium aluminate salts have poorer air tolerance but Li[Al(hfip)4] resulted in superior battery cycling, with lower overpotentials for plating and st
Fluorine-Free Electrolytes for Lithium and Sodium …
With the initial quest for alternative anions to be used in batteries, Johansson developed computational approaches to correlate the anion''s structure with its oxidation stability leading to a wide range of …
Ether‐Modified Nonflammable Phosphate Enabling Anion‐Rich …
Ether-Modified Nonflammable Phosphate Enabling Anion-Rich Electrolyte for High-Voltage Lithium Metal Batteries. ... DMEP-LHCE exhibits enhanced safety than that of TEP-LHCE, suggesting its versatility and potential for next-generation lithium metal batteries. Conflict of …
Anion‐Regulated Weakly Solvating …
Development of advanced high-voltage electrolytes is key to achieving high-energy-density lithium metal batteries (LMBs). Weakly solvating electrolytes (WSE) can …
In-depth exploration of the effect mechanisms of …
Lithium salts exert a great influence on the electrochemical performance of lithium metal batteries. Dissociated Li-ions present rapid transfer dynamics through solvation with a solvent in liquid batteries or …
Borates vs . aluminates: comparing the anion for lithium-ion …
Electrolyte salts with a weakly-coordinating anion are known to improve the cyclability of lithium-ion batteries (LIBs) by offering high ionic conductivity,1–3 as a result of …
High-rate cathode CrSSe based on anion reactions …
Studies of transition metal dichalcogenides (TMDs) can be traced back to the 1970s but they have been abandoned for a while due to the fire hazard of lithium metal batteries. Herein, a new layered material, CrSSe, is reported, whose …
Multi-anion electrolyte modulates the interactions in solvation ...
Designing anion-dominated weak solvation structures is often achieved by elevating the concentration of Li salts. However, this is accompanied by the increase in the cost. Herein, a medium concentration electrolyte (∼1 M) with weak solvation structures is established by the multi-anion strategy. Multiple anions in the electrolyte strengthen the anion-solvent interactions …
Anion‐repulsive polyoxometalate@MOF‐modified separators for …
With the growing demand for electric facilities and energy storage devices, high-energy-density lithium batteries with lithium metal as the anode have attracted significant attention due to the high theoretical capacity (3680 mAh g −1) and low electrochemical potential (−3.04 V vs SHE) of lithium metal.
Progresses on advanced electrolytes engineering for high-voltage ...
This enables the NCM622 lithium battery to cycle stably at an ultra-high voltage of 4.9 V and 200 cycles at 0.3C, achieving a capacity retention rate of 74.0 %, showing great potential for practical applications. ... Regulating anions in the solvation sheath of lithium ions for stable lithium metal batteries. ACS Energy Lett., 4 (2019), pp. 411 ...
Anion chemistry in energy storage devices
For instance, Li-S batteries with an LiTFSI-based electrolyte delivered a much more stable cycling performance compared with batteries with a lithium bis …
Understanding anion-redox reactions in cathode materials of lithium …
Li-ion batteries (LIBs) have garnered wide interest since the first commercial LIBs were produced by Sony in 1991 [1–3].With the advances in analytical research, significant efforts in studying the fundamental electrochemistry of conventional battery materials have been made (e.g. LiCoO 2 as the cathode and graphite as the anode) [4–6] bsequent …
Ion Chromatography for Battery Material Testing
Speciation Analysis of Manganese Dissolution Product in Li-ion Batteries; Analysis of Phosphate and Manganese Degradation Products in Aged Lithium-Ion Batteries by IC and HRMS; Develop Higher Density Materials for Li-ion Batteries; Characterization of Battery Materials: Test Cases for the Energy Storage of Tomorrow
Improving the rate performance of mesophase pitch fluoride by …
Mesophase pitch fluoride (MPF) has emerged as a promising cathode material for lithium/fluorinated carbon primary batteries (Li/CF x) owing to its economic viability and high capacity.However, the rate performance of MPF cathodes is severely compromised by irregular LiF discharge products, which impede lithium-ion diffusion at the electrode interface and within …
Designer Anions for Better Rechargeable Lithium …
Here, salt anions for lithium and other monovalent (e.g., sodium and potassium) and multivalent (e.g., magnesium, calcium, zinc, and aluminum) rechargeable batteries are outlined. Fundamental considerations on the design of salt …
Borates vs. aluminates: comparing the anion for lithium-ion batteries
salts were investigated, allowing comparisons between the anions to be made, and their suitability as electrolyte salts for battery use was explored. The syntheses of the lithium borate and lithium aluminate salts were adapted from previous reports, 15,23 involving the addition of pure lithium borohydride or lithium aluminium hydride to hexafluor-
Lithium-ion battery
OverviewSafetyHistoryDesignBattery designs and formatsUsesPerformanceLifespan
The problem of lithium-ion battery safety has been recognized even before these batteries were first commercially released in 1991. The two main reasons for lithium-ion battery fires and explosions are related to processes on the negative electrode (cathode). During a normal battery charge lithium ions intercalate into graphite. However, if the charge is forced to go too fast (or at …
Stable low-temperature lithium metal batteries with dendrite-free ...
Within the rapidly expanding electric vehicles and grid storage industries, lithium metal batteries (LMBs) epitomize the quest for high-energy–density batteries, given the high specific capacity of the Li anode (3680mAh g −1) and its low redox potential (−3.04 V vs. S.H.E.). [1], [2], [3] The integration of high-voltage cathode materials, such as Ni-contained LiNi x Co y …
Anion-enrichment interface enables high-voltage anode-free lithium …
Solvents with low solvating power will be defeated by anions of weakly dissociated lithium salts 30,55, ... X. et al. High-energy rechargeable metallic lithium battery at −70 °C Enabled by a ...
Anion-Induced Interfacial Liquid Layers on …
The incompatibility of lithium intercalation electrodes with water has impeded the development of aqueous Li-ion batteries. The key challenge is protons which are generated by water …
Bis(fluorosulfonyl)imide-based electrolyte for rechargeable lithium ...
The inherent properties of non-aqueous electrolytes are highly associated with the identity of salt anions. To build highly conductive and chemically/electrochemically robust electrolytes for lithium-ion batteries (LIBs) and rechargeable lithium metal batteries (RLMBs), various kinds of weakly coordinating anions have been proposed as counterparts of lithium …
A promising bulky anion based lithium …
1. Introduction Current Li-ion batteries (LIBs) are widely used for portable electronics, electric vehicles, and stationary grid-energy storage devices. 1,2 The salt in LIBs plays a critical role in …
Rechargeable anion-shuttle batteries for low-cost energy storage
As promising alternatives to lithium-ion batteries, rechargeable anion-shuttle batteries (ASBs) with anions as charge carriers stand out because of their low cost, long cyclic lifetime, and/or high energy density. In this review, we provide for the first time, comprehensive insights into the anion shuttling mechanisms of ASBs, including anion ...
Research Progress on Solid-State Electrolytes in Solid-State Lithium ...
Solid-state lithium batteries exhibit high-energy density and exceptional safety performance, thereby enabling an extended driving range for electric vehicles in the future. ... while single-ion polymer electrolytes involve lithium ion pairing with an anion on a segment of the modified polymer chain to form an ionic bond [19,20]. As a solid ...
Design of sulfonimide anions for rechargeable lithium …
In this work, a historical overview of the development of sulfonimide anions in the field of electrolyte materials is presented, and the unique features of sulfonimide anions are discussed, in comparison with some …
Rechargeable anion-shuttle batteries for low-cost energy storage
As promising alternatives to lithium-ion batteries, rechargeable anion-shuttle batteries (ASBs) with anions as charge carriers stand out because of their low cost, long cyclic …
Borates vs. aluminates: comparing the anion for lithium-ion batteries …
Lithium borate and aluminate salts bearing a hexafluoroisopropoxy ligand have been prepared and investigated for use in lithium-ion batteries and Cu‖Li cells. Lithium aluminate salts have poorer air tolerance but Li[Al(hfip)4] resulted in superior battery cycling, with lower overpotentials for plating and st ChemComm 60th Anniversary Collection
Cationic and anionic redox in lithium-ion based …
Lithium-ion batteries have proven themselves to be indispensable among modern day society. Demands stemming from consumer electronics and renewable energy systems have pushed researchers to strive …
Insight into anion storage batteries: Materials, properties and ...
Research on the storage of anions can not only develop anion batteries, but also extend it to more novel battery concepts such as desalination batteries and dual-ion …
Anion charge and lattice volume dependent lithium ion migration …
Heat maps of the calculated E m of lithium ion migration between two adjacent Oct and Tet central sites in the artificial fcc-type a oxygen and b sulfur anion sublattices, and energy differences ...